Environmental Fact Sheets, Treatment of air and gas : Regenerative thermal oxidation (biotox®) - Biothermica Technologies Inc., Enviro-Access
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Environmental Fact Sheets

Treatment of air and gas : Regenerative thermal oxidation (biotox®) - Biothermica Technologies Inc. (F2-01-95)

Description of the technology

The Biotox regenerative oxidation process designed by Biothermica Technologies Inc. solves air pollution problems related to industries emitting volatile organic compounds (VOCs), condensible organic compounds (COCs), polycyclic aromatic hydrocarbons (PAHs), and total reduced sulfurs (TRS). Some of these contaminants (and occasionally all of them) can be found in emissions from the following industries:

 

  • asphalt paper and shingles manufacturing;
  • graphic arts and printing;
  • surface coverings;
  • pharmaceuticals;
  • painting process;
  • anode manufacturing for aluminum plants;
  • oxidation of asphalt;
  • thermoplastic resins;
  • rendering plants;
  • sludge treatment plants;
  • Kraft mills.

 

The bituminous droplets in some types of industrial waste are hard to remove. They tend to adhere to the walls of air treatment equipment and ignite. Simultaneous treatment of VOCs and COCs with Biotox involves preheating of the incoming gases above their dew point prior to enter the Biotox unit.. Each of the Biotox heat recuperation chambers has ceramic modules which store recovered heat in order to transfer it to the incoming gases.

Performance

The process allows the industry to meet Quebec's environmental standards on VOCs and also provides energy recovery from 80 % to 97 % on the process to be treated.


It treats VOCs and COCs simultaneously and is over 98% effective in destroying them; current standards call for 90% effectiveness in destroying VOCs. The process produces neither wastewater nor dangerous and hard-to-treat wastes, and it does not transfer pollutants to the water or soil.


The technology consumes less energy than other oxidation technologies (recuperative and catalytic oxidation), which treat pollutant concentrations of less than 3 g/Nm3. With these other technologies, the cost of equipment maintenance is higher because of frequent contamination of the catalysts by sulphur or halogen compounds in VOCs and COCs; this is not a problem with Biotox technology.

Limitations

The Biotox process can be used when the VOC concentration is less than 4 g/Nm3 and the air stream flow is higher than 4,000 Nm3/h.

Installation and operation


The size of the system varies with the air stream flow rate and type of pollutant to be treated.


The Biotox process is fully automated and requires minimal human intervention. Workers do not need to take any special protective measures.


If the concentration of VOCs and COCs exceeds 2 g/Nm3, the Biotox process would run without an external energy source, but otherwise it will be necessary to use natural gas, propane or lignt oil to maintain the temperature in the combustion chamber at its normal set point (750°C - 850 °C) . Recovery of energy from the process itself is always very high, limiting to the minimum, outside energy use.

Costs

The typical purchase price of a Biotox system, including installation, is about $25/Nm3 for a stream flow of about 35,000 Nm3/h.

Additional information

The Biotox process was developed in Quebec by Biothermica. The R&D work lasted six years and cost at $750,000, with contributions from the National Research Council of Canada, the MER [Quebec Ministry of Energy and Resources] and Environment Canada. In 1994, Biothermica won the Canadian Award for Business Excellence (innovation category) as a result of its work on Biotox. In 1997, the Ministère de l'Environnement du Québec presented Biothermica with the Mérite Environnemental prize (100 employees and less business category) for its latest installations in a Kraft mill (Cascades, East-Angus) and in an aluminum anode manufacturer (Lauralco, Deschambault).


Almost twenty biotox units have been conceived for diverse applications as follows :

CompanyInstallation yearCapacity
(Nm3/H)
No. of beds
Asphalt paper manufacturing   
N.A.F. - Joliette, QC199117 0003
Emco Building Products- Ville LaSalle, QC199325 5003
Emco Building Products - Ville LaSalle, QC199534 0003
Emco Building Products- Edmonton, AB199739 0003
Certain Teed Roofing Products Group, Blue Bell, USA 200346 0003
N.A.F. Joliette, Qc 200559 500 3
Anode manufacturing for aluminum plants   
Aluminerie Lauralco - Deschambault, QC199710 0003
Kraft mill   
Cascades - East-Angus, QC199725 5003
Paint Application   
Bombardier-Canadair, Ville St-Laurent, QC199617 0002
OSRAM-Sylvania, Drummondville, QC199955 0002
Bombardier, Dorval, Qc200134 0003
Printing   
Institut des communications graphiques,
Montréal, QC
19973 4002
Oberthur, Jeux et Technologies, Mtl, Qc200130 6002
Quebecor World, Magog, Qc200434 0002
Textile   
Paris Star, Montréal QC199915 300 2
Magnesium Production   
Magnola, Asbestos, QC19993 X 8 5003
Floor coverings   
Tarkett Inc, Farhnam, Qc2000119 0002
Petrochemicals   
Raffineries de Napierville, Napierville, Qc20025 1002
Food Industry   
McCain Foods USA, Presque Ile, Maine2004136 0002

Contacts

Biothermica Technologies Inc.
M. Raphaël Bruneau, Project Manager
426, Sherbrooke Street East
Montreal, Quebec, H2L 1J6
 
Phone :(514) 488-3881 #234
Fax :(514) 488-3125
E-Mail :raphael.bruneau@biothermica.com
Web site :http://www.biothermica.com